Corrosion Protection Benefits of Electroless Nickel Plating

By Matt Lindstedt, Technical Sales Manager

Electroless Nickel Plating: Superior Corrosion Protection

Electroless Nickel Corrosion Protection

Raw metals other than precious metals can easily oxidize and corrode over time when exposed to various environmental conditions and corrosive applications.  The proper design of any component must begin with a surface engineering evaluation to ensure that the product will function reliably over the intended service life.  Even in relatively mild service applications, corrosion can result in functional issues and shortfalls.  Electroless nickel plating can provide a robust solution to corrosive attack across a range of corrosive mechanisms including galvanic corrosion, chemical attack and erosion. Electroless nickel plating (EN) can be applied to a wide range of basis metals including steel, copper, brass and aluminum alloys. Electroless Nickel plating is currently utilized to promote corrosion protection performance across a diverse range of industries including heavy equipment, oil & gas, power transmission & distribution, automotive, marine and railway to name a few.

Electroless Nickel Plating Characteristics

EN is different from electrolytic nickel plating in that is does not require an external source of electrons for deposition. This auto-catalytic process does not need to pass electric current through parts to form the plated deposit which gives the EN deposit greatly improved uniformity over that of electrolytic deposits.  The improved uniformity of ENP is a principle deposit property that enhances corrosion resistance on all features of a part especially in features that are traditionally difficult to coat such as thru holes or counter bores.  Another unique characteristic of ENP is that the nickel co-deposits phosphorus of varying amounts from 4-13% based on the bath type. The level of phosphorus directly impacts key deposit properties such as hardness, corrosion resistance and ductility.  In addition, post-plate heat treatment can be used to alter the structure of the electroless nickel plating thereby increasing hardness to as high as 70 Rc.

Advanced Electroless Nickel Plating OptionsElectroless Nickel Plating Corrosion Protection

Advanced Plating Technologies has developed processes to further enhance the corrosion performance of electroless nickel plating by utilizing a multi-layer or duplex systems consisting of an underplate of copper and/or electrolytic nickel prior to the electroless nickel deposit.  APT also offers proprietary sealing technologies such as our H4 and H5 molecular sealers that can increase the salt spray performance of ENP by as much as 2x.

Types of Electroless Nickel Plating – Corrosion Protection Options

Traditional electroless nickel phosphorus plating is broken down into three specific groups, 1) low phosphorus (<5% P), medium phosphorus (6-10% P) and high phosphorus (11-13% P).  Depending upon design considerations and the corrosion performance required, the phosphorus level and deposit thickness can be adjusted accordingly. Advanced Plating Technologies offers both medium phosphorus electroless nickel plating and high phosphorus ENP. A breakdown of each EN type is provided below:

  • High Phosphorus (11-13% P): High phosphorus electroless nickel plating (high-phos) provides the greatest corrosion resistance, is non-magnetic, has the lowest melting point (~ 880C) and is the most ductile of the EN deposits. As-plated the deposit has an amorphous structure with a hardness between 48-55 Rc that can be increased to 66-70 Rc with post-plate heat treatment. Due to the amorphous structure, high phosphorus electroless nickel has the lowest as-plated internal stress making it the best electroless nickel for heavy build deposits capable of being plated to thicknesses of up to 0.005 inches per side.  The deposit tends to have a semi-bright appearance that will vary based upon the raw surface finish of the plated part.  High phosphorus electroless nickel has a slower plating rate as compared to medium phosphorus electroless nickel which can increase cost.Medium Phosphorus Electroless Nickel Plating Corrosion Protection
  • Medium Phosphorus (6-10% P):  Medium phosphorus electroless nickel (mid-phos) is often referred to as the “work horse” electroless nickel.  It provides good corrosion resistance, solderability and a higher melting point (~1000 C).  Mid-phos electroless nickel plates in a mixed amorphous/micro crystalline state and has a hardness of 58-62 Rc as plated and can be increased to 66-70 Rc with post-plate heat treatment options.  Medium phosphorus electroless nickel plating has a semi-bright to bright appearance that will vary based on the raw surface finish of the part.  A common advantage to using mid-phosphorus EN plating is the faster plating rate which can reduce cost over high-phos EN.
  • Low Phosphorus (5% or less P): A low-phosphorus electroless nickel plating (low-phos) provides the highest as-plated hardness (up to 60 Rc) and is the least ductile due to the micro-crystalline as-plated structure. Low-phos is also the least corrosion resistant of the three electroless nickel types but is the most conductive and solderable in the as-plated state.  Fewer metal finishing job shops offer low phosphorus electroless nickel plating since there is typically a much higher commercial demand for medium or high phosphorus varieties.

APT has compiled a summary Technical Data Sheet to provide a simple one-sheet reference on the various properties of electroless nickel plating.  Select on the image below to view, print or save this reference.

Electroless Nickel Technical Data Sheet

Heat Treatment of Electroless Nickel Plating

A common question asked regarding electroless nickel plating is how heat treatment will affect the deposit properties.  A brief summary of heat treatments are provided below:

Preplate Bakes:  Some specifications recommend preplate bakes and/or shot peening of higher stress ferrous alloys to promote adhesion and reduce the risk of hydrogen embrittlement.  Preplate bakes do not immediately affect the properties of subsequent ENP.

Low Temperature Postplate Bakes (< 500F):  These bakes are often used to promote adhesion especially on aluminum alloys and relieve hydrogen embrittlement in ferrous alloys.  No appreciable change in deposit properties occur with these lower temperature bakes.

High Temperature Postplate Bakes (500F-750F):  These bakes are often used to transition amorphous structure to crystalline structure in both medium and high phosphorus electroless nickel plating.  Due to the structure change of the deposit both the hardness increases and corrosion resistance decreases.

Advanced Plating Technologies offers controlled heat treatment of EN that reduces or can even fully eliminate cosmetic changes in the appearance of EN deposits (such as darkening) during baking.  In addition, APT offers a family of proprietary sealers that can enhance the corrosion protection performance of high-temperature baked electroless nickel deposits to offset and reductions in overall corrosion protection performance.

Summary of Electroless Nickel PlatingHigh Phosphorus Electroless Nickel Plating Corrosion Protection

Electroless nickel plating is engineered finish that can be used to increase the corrosion resistance of various basis metals including cuprous, ferrous and aluminum alloys. The lack of applied current when plating auto-catalytic electroless nickel results in excellent deposit uniformity on even most complex shapes.   In addition to enhancing corrosion protection performance, electroless nickel plating can be used to improve hardness, wear resistance, lubricity, solderability and appearance of components.  The phosphorus content of the deposit affects the characteristics of the final finish.  Post-plate heat treatments can be used to promote both the adhesion and hardness of electroless nickel plating.

You can find more information on our electroless nickel plating services page as well as contact a member of our technical sales staff to discuss your specific application further.  Quote requests for electroless nickel plating of any other finish Advanced Plating Technologies offers can be submitted directly through our RFQ page.

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